Structural Elucidation and Electrochemiluminescence on a 3D Cadmium(II) MOF with 5-c Topology

نویسندگان

چکیده

A novel cadmium(II) based MOF, [Cd(?–ppza)]n (1) (H2ppza = 3–(pyridin–4–yl)–1H–pyrazole–5–carboxylic acid) was synthesized under solvothermal condition. The single-crystal X-ray diffraction reveals that the title MOF 1 crystallizes in triclinic system with P–1 space group, and each Cd(II) is coordinated five (Hppza)2? ions forming a distorted octahedron. carboxylic group ligand acts as bridge linking into 3D structure. has 5-c {46.64} topological Furthermore, exhibits good electrochemiluminescence (ECL) behavior.

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ژورنال

عنوان ژورنال: Journal of Inorganic and Organometallic Polymers and Materials

سال: 2022

ISSN: ['1574-1451', '1574-1443']

DOI: https://doi.org/10.1007/s10904-022-02236-w